2,4,5-Trichlorophenol (2,4,5-TCP) is one of the most toxic chlorophenols (C
Ps) and is very difficult to be biodegraded. The establishment of an approp
riate treatment which is friendly to the earth environment for 2,4,5-TCP is
an urgent matter to be solved. Total organic carbon (TOC) removal of the s
ynthetic wastewater which contains 2,4,5-TCP at TOC of 405 g/m(3) has been
carried out by using hydrogen peroxide and ultraviolet irradiation (H2O2/UV
). Experiments were carried out in a batch reactor with a low pressure UV l
amp (500 W) irradiating ultraviolet at 254 nm and at 185 nm (5%). The chemi
cal compounds included in the synthetic wastewater have been completely rem
oved in the presence of hydrogen peroxide. It was found that the optimum co
ncentration of hydrogen peroxide, which was added initially, exists.