Pyridazines 93. An unexpected reaction behaviour of 3-aminopyridazine towards 2-methylphenylisocyanate

Citation
G. Heinisch et al., Pyridazines 93. An unexpected reaction behaviour of 3-aminopyridazine towards 2-methylphenylisocyanate, J HETERO CH, 38(4), 2001, pp. 945-948
Citations number
12
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF HETEROCYCLIC CHEMISTRY
ISSN journal
0022152X → ACNP
Volume
38
Issue
4
Year of publication
2001
Pages
945 - 948
Database
ISI
SICI code
0022-152X(200107/08)38:4<945:P9AURB>2.0.ZU;2-G
Abstract
Reaction of 3-aminopyridazine (1) with 2-methylphenylisocyante (4) affords not only the desired urea derivative (5) but also an unexpected side-produc t (6), which could be identified as the corresponding biuret derivative by means of elemental and spectroscopic data as well as crystal structure dete rmination.