Thick GaAsN layers and GaInNA/GaAs multiple quantum wells (MQWs) were succe
ssfully grown on semi-insulating GaAs substrates by gas-source molecular be
am epitaxy equipped with a nitrogen radio frequency (rf) activated plasma s
ource. High resolution x-ray rocking curves indicate that the nitrogen cont
ent in the GaAsN layer is increased from 0.7% to 3% with increasing rf cavi
ty pressure. Room temperature photoluminescence measurements show that the
emission wavelength decreases when the nitrogen content is increased. The e
volution of the strained band gap with nitrogen composition is in quantitat
ive agreement with calculations as well as with other spectroscopic studies
, allowing complete characterization of the alloy for a small nitrogen frac
tion. Furthermore, the influence of the growth temperature and the V-III ra
tio on the optical and structural properties of the GaInNAs MQWs has been c
arefully examined. We found that the material properties are optimal at a g
rowth temperature of 400 degreesC and a V-III ratio of 3. (C) 2001 American
Vacuum Society.