Polypropene product innovation by reactor granule technology

Citation
G. Cecchin et al., Polypropene product innovation by reactor granule technology, MACRO SYMP, 173, 2001, pp. 195-209
Citations number
8
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
MACROMOLECULAR SYMPOSIA
ISSN journal
10221360 → ACNP
Volume
173
Year of publication
2001
Pages
195 - 209
Database
ISI
SICI code
1022-1360(200107)173:<195:PPIBRG>2.0.ZU;2-M
Abstract
Continuous fine tuning of both chemistry and architecture of heterogeneous, isospecific MgCl2/TiCl4 catalyst systems for propene polymerization has le d to a significant improvement in their performances in terms of activity, stereoselectivity, and capability to control both molecular parameters and morphology of the resulting polymers. As a result, a number of improved/inn ovative propene-based products has recently been developed that clearly out perform the previously available materials. In particular, a family of reac tor-grade polymers has been synthesized including homopolymers and heteroph asic copolymers offering, respectively, an unprecedented relationship betwe en fluidity and stiffness and between stiffness and impact strenght, and su persoft polypropene alloys that could not have been achieved even via mecha nical blending.