Photopolymerization of epoxides with platinum(II) bis(acetylacetonato)/silane catalysts

Authors
Wang, F Neckers, DC
Citation
F. Wang et Dc. Neckers, Photopolymerization of epoxides with platinum(II) bis(acetylacetonato)/silane catalysts, MACROMOLEC, 34(18), 2001, pp. 6202-6205
Citations number
16
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
MACROMOLECULES
ISSN journal
00249297 → ACNP
Volume
34
Issue
18
Year of publication
2001
Pages
6202 - 6205
Database
ISI
SICI code
0024-9297(20010828)34:18<6202:POEWPB>2.0.ZU;2-D
Abstract
Photopolymerization of epoxides in the presence of silanes RSi3H and platin um(II) bis(acetylacetonato) complexes is reported. The catalytic reactivity of the platinum complexes depended on the concentration ratio of silane/pl atinum complex to monomer and the molecular structure of the silanes, as we ll as the structure of the platinum complexes. A mechanism is proposed.