Studies on photoconductivity of C-60 and C-60-doped poly(vinylchloride)

Single crystals of buckminsterfullerene (C-60) were grown by low-temperatur e solution growth technique. Using the same technique, poly(vinylchloride) was doped with ITO of C-60 by mass. FTIR spectra were recorded for pure C-6 0, pure poly(vinylchloride) and C-60-doped poly(vinylchloride) by Bruker IF S 66V FTIR spectrometer. From the nature of the FTIR spectrum of the C-60-d oped material, it is found that the material is polycrystalline and the pre sence of C-60 has been confirmed. The absorption spectra for C-60 and C-60- doped PVC samples were recorded using SL159 UV-vis spectrophotometer. Photo conductivity studies were also made for these materials. It was interesting to observe that the C-60-PVC exhibited negative photoconductivity. Stockma nn model has been successfully applied to explain this behaviour of the dop ed sample. (C) 2001 Elsevier Science B.V. All rights reserved.