B(C6F5)(3)-catalyzed allylation of secondary benzyl acetates with allylsilanes

Authors
Rubin, M Gevorgyan, V
Citation
M. Rubin et V. Gevorgyan, B(C6F5)(3)-catalyzed allylation of secondary benzyl acetates with allylsilanes, ORG LETT, 3(17), 2001, pp. 2705-2707
Citations number
20
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANIC LETTERS
ISSN journal
15237060 → ACNP
Volume
3
Issue
17
Year of publication
2001
Pages
2705 - 2707
Database
ISI
SICI code
1523-7060(20010823)3:17<2705:BAOSBA>2.0.ZU;2-0
Abstract
[GRAPHICS] A highly effective protocol for allylation of secondary benzylic alcohol de rivatives with allylsilanes in the presence of catalytic amounts of B(C6F5) (3) has been developed. Some additional functionalities, such as bromo, ace toxy, and primary benzyloxy groups, were tolerated under these conditions.