Samarium-mediated tandem reactions of o-carborane. Synthesis and molecularstructure of [{eta(5):eta(1):eta(6)-Me2Si(C(9)H(5)CH(2)CH(2)G) (C2B10H10)Sm}(2)(mu-Cl)][Li(THF)(4)](G = NMe2 and OMe)

Authors
Wang, SW Li, HW Xie, ZW
Citation
Sw. Wang et al., Samarium-mediated tandem reactions of o-carborane. Synthesis and molecularstructure of [{eta(5):eta(1):eta(6)-Me2Si(C(9)H(5)CH(2)CH(2)G) (C2B10H10)Sm}(2)(mu-Cl)][Li(THF)(4)](G = NMe2 and OMe), ORGANOMETAL, 20(17), 2001, pp. 3624-3625
Citations number
14
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
20
Issue
17
Year of publication
2001
Pages
3624 - 3625
Database
ISI
SICI code
0276-7333(20010820)20:17<3624:STROOS>2.0.ZU;2-Y
Abstract
New metallacarboranes bearing a (nido-RC2B10H10)(2)(4-) ligand, [{eta (5):e ta (1):eta (6)-MeSi(C(9)H(5)CH(2)CH(2)G)-(C2B10H10)Sm}(2)(mu -Cl)][Li(THF)( 4)] (G = NMe2 (1), OME (2)), have been prepared and structurally characteri zed by treatment of SmI2(THF)(x) with 1 equiv of [Me2Si(C9H5-CH(2)CH(2)G)(C 2B10H10)]Li-2(OEt2)(2). LiCCl in THF via unexpected samarium-mediated tande m reactions.