Aqueous organometallic chemistry with nitrogen ligands: Synthesis of hydrophilic platinum(0) olefin complexes

Authors
Kundu, A Buffin, BP
Citation
A. Kundu et Bp. Buffin, Aqueous organometallic chemistry with nitrogen ligands: Synthesis of hydrophilic platinum(0) olefin complexes, ORGANOMETAL, 20(17), 2001, pp. 3635-3637
Citations number
33
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
20
Issue
17
Year of publication
2001
Pages
3635 - 3637
Database
ISI
SICI code
0276-7333(20010820)20:17<3635:AOCWNL>2.0.ZU;2-2
Abstract
Reactions of hydrophilic unsymmetrical pyridine-imine chelating ligands wit h pt(eta (2)-norbornene)(3) in the presence of olefins that contain electro n-withdrawing substituents afford water-soluble three-coordinate Pt-(0) com plexes. The stability of these organometallic complexes in aqueous solution is dependent on the position of the hydrophilic charged substituents in th e chelating ligand and the electronic nature of the coordinated olefin.