Synthesis of the metal-containing dinitrile ligand trans-[Ru((CNBu)-Bu-t)(2){(PPh2)(2)CCN}(2)] as a precursor of polymetallic species

Authors
Mosquera, MEG Ruiz, J Riera, V Garcia-Granda, S Diaz, MR Bois, C
Citation
Meg. Mosquera et al., Synthesis of the metal-containing dinitrile ligand trans-[Ru((CNBu)-Bu-t)(2){(PPh2)(2)CCN}(2)] as a precursor of polymetallic species, ORGANOMETAL, 20(17), 2001, pp. 3821-3824
Citations number
34
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
20
Issue
17
Year of publication
2001
Pages
3821 - 3824
Database
ISI
SICI code
0276-7333(20010820)20:17<3821:SOTMDL>2.0.ZU;2-C
Abstract
The complex trans-[Ru((CNBU)-B-t)(2){(PPh2)(2)-CCN}(2)] (2) has been prepar ed by reaction of trans-[Ru((CNBu)-Bu-t)(2){(PPh2)(2)CH}(2)] with (CN)2. 2 behaves as a dinitrile metalloligand, allowing the synthesis of the new pol ymetallic species trans-[Ru((CNBu)-Bu-t)(2){(PPh2)(2)CCN-Au(PPh3)}(2)](2+) (3), trans-[Ru((CNBu)-Bu-t)(2){(PPh2)(2)CCN-RuCl2(C6H6)}(2)] (4), and trans -[Ru((CNBu)-Bu-t)(2){(Ph2P)(2)CCN-Cu-NCC(Ph2P)(2)}](n)(+) (5), when treated with the appropriate metallic fragment.