Synthesis and structural characterization of monomeric three-coordinated, beta-diketoiminate organozinc derivatives

Authors
Prust, J Stasch, A Zheng, WJ Roesky, HW Alexopoulos, E Uson, I Bohler, D Schuchardt, T
Citation
J. Prust et al., Synthesis and structural characterization of monomeric three-coordinated, beta-diketoiminate organozinc derivatives, ORGANOMETAL, 20(17), 2001, pp. 3825-3828
Citations number
21
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
20
Issue
17
Year of publication
2001
Pages
3825 - 3828
Database
ISI
SICI code
0276-7333(20010820)20:17<3825:SASCOM>2.0.ZU;2-U
Abstract
The monomeric zinc compounds with three-coordinated zinc (dipp)NacNacZnCl ( 1), (dipp)NacNacZnMe (2), (dipp)NacNacZntBu (3), and (dipp)NacNacZnPh (4) w ere prepared under mild conditions in strong coordinating donor solvents. C ompounds 2-4 have been structurally characterized. The beta -diketoiminate ligand (2-((2,6-diisopropylphenyl)amino)-4-((2,6-diisopropylphenyl)imino)pe nt-2-ene) ((dipp)NacNac) acts as a chelating ligand through its two N atoms , forming a six-membered ring with the zinc atom.