Direct phase determination of surface in-plane reflection is realized for t
hin films on substrates by using substrate reflections as an intermediary t
o enhance the coherent interaction in resonant multiwave grazing incidence
diffraction in thin films. The coupling of the in-plane diffracted waves at
the interface between the thin film and the substrate is essential, The in
tensity variation due to this enhanced interaction/coupling becomes clearly
visible, thus leading to unambiguous phase determination. This opens a dif
ferent way for direct phase determination of surface reflections in thin fi
lms.