Electrons floating above liquid helium form an ideal two-dimensional system
with an extremely high mobility. However, the mobility can change substant
ially when decreasing the thickness of the helium film from bulk to a thin
film of a few hundred Angstrom. Furthermore it is observed that for certain
film thicknesses there is a pronounced dip in the mobility. We present the
oretical investigations and measurements concerning this problem. Taking in
to account the roughness of the substrate, which supports the helium film,
we find theoretically a discontinuity in the chemical potential of the elec
trons which results in a diplike behavior in the electron current and hence
in the electron mobility. This scenario is supported by direct measurement
s of the electron current on substrates with different roughness and at dif
ferent electron densities.