Binding of similarly charged plates with counterions only - art. no. 078301

Citation
Ag. Moreira et Rr. Netz, Binding of similarly charged plates with counterions only - art. no. 078301, PHYS REV L, 8707(7), 2001, pp. 8301
Citations number
20
Categorie Soggetti
Physics
Journal title
PHYSICAL REVIEW LETTERS
ISSN journal
00319007 → ACNP
Volume
8707
Issue
7
Year of publication
2001
Database
ISI
SICI code
0031-9007(20010813)8707:7<8301:BOSCPW>2.0.ZU;2-5
Abstract
Similarly and highly charged plates in the presence of multivalent counteri ons attract each other and form electrostatically bound states. Using Monte -Carlo simulations, we obtain the interplate pressure in the global paramet er space. The equilibrium plate separation, where the pressure changes from attractive to repulsive, exhibits a novel unbinding transition. A systemat ic and asymptotically exact strong-coupling field theory yields the bound s tate from a competition between counterion entropy and electrostatic attrac tion, in agreement with simple scaling arguments and simulations.