Two new coordination polymers differentiated by C-H center dot center dot center dot O hydrogen bonding - synthesis and crystal structure of [(oxa)M(DPA)]

Authors
Lu, JY Schroeder, TJ Babb, AM Olmstead, M
Citation
Jy. Lu et al., Two new coordination polymers differentiated by C-H center dot center dot center dot O hydrogen bonding - synthesis and crystal structure of [(oxa)M(DPA)], POLYHEDRON, 20(19), 2001, pp. 2445-2449
Citations number
23
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
POLYHEDRON
ISSN journal
02775387 → ACNP
Volume
20
Issue
19
Year of publication
2001
Pages
2445 - 2449
Database
ISI
SICI code
0277-5387(20010830)20:19<2445:TNCPDB>2.0.ZU;2-Q
Abstract
Two new coordination polymers, [(oxa)Fe(DPA)] (1) (DPA = 2,2-dipyridylamine . oxa = oxalate) and [(oxa)Ni(DPA)] (2). were synthesized through a self-as sembly chemical process under hydrothermal conditions, and characterized by single crystal structures. The C-H . . .O hydrogen bonds in 1 and 2 play i mportant roles in the crystal packing of the two new compounds. (C) 2001 El sevier Science Ltd. All rights reserved.