The nature of the super-electron-releasing inductive effect of the silatranyl group and its spectroscopic and chemical consequences

Authors
Voronkov, MG Brodskaya, EI Belyaeva, VV Lazareva, NF
Citation
Mg. Voronkov et al., The nature of the super-electron-releasing inductive effect of the silatranyl group and its spectroscopic and chemical consequences, RUSS CHEM B, 50(5), 2001, pp. 757-763
Citations number
80
Categorie Soggetti
Chemistry
Journal title
RUSSIAN CHEMICAL BULLETIN
ISSN journal
10665285 → ACNP
Volume
50
Issue
5
Year of publication
2001
Pages
757 - 763
Database
ISI
SICI code
1066-5285(200105)50:5<757:TNOTSI>2.0.ZU;2-4
Abstract
The relationship between the structure of carbofunctionally substituted 1-m ethylsilatranes XCH2Si(OCHRCH2)(3)N (R = H, Me; X = R ' N-2, R 'S, Cl, etc. , R ' = Alk), the unusually high electron-releasing properties of the silat ranyl group, and the enhanced chemical reactivity of the exocyclic XCH2 sub stituent is discussed.