Synthesis and liquid-crystalline properties of substituted beta-aminovinylketones and their complexes with copper(II)

Authors
Turanova, OA Galyametdinov, YG Ovchinnikov, IV
Citation
Oa. Turanova et al., Synthesis and liquid-crystalline properties of substituted beta-aminovinylketones and their complexes with copper(II), RUSS CHEM B, 50(5), 2001, pp. 805-808
Citations number
13
Categorie Soggetti
Chemistry
Journal title
RUSSIAN CHEMICAL BULLETIN
ISSN journal
10665285 → ACNP
Volume
50
Issue
5
Year of publication
2001
Pages
805 - 808
Database
ISI
SICI code
1066-5285(200105)50:5<805:SALPOS>2.0.ZU;2-C
Abstract
Mesogenic complexes were synthesized by the reaction of beta -aminovinyl ke tones with copper(II) acetate. On going from the ligands to complexes, the temperature of phase transitions increases and the nematic phase disappears . The initial members of the homological 1-(4-nonyloxyphenyl)-3-(4-methoxyp henylamino)-1-propen-1-one series demonstrate the alternation of clearing t emperatures, which is absent for the corresponding copper(II) complexes.