The preparation and reactivity of metal-containing monomers 54. Thermolysis of the acrylamide monomer [Co(CH2=CHCONH2)(4)(H2O)(2)](NO3)(2)

Authors
Rozenberg, AS Raevskii, AV Aleksandrova, EI Kolesova, OI Dzhardimalieva, GI Pomogailo, AD
Citation
As. Rozenberg et al., The preparation and reactivity of metal-containing monomers 54. Thermolysis of the acrylamide monomer [Co(CH2=CHCONH2)(4)(H2O)(2)](NO3)(2), RUSS CHEM B, 50(5), 2001, pp. 901-906
Citations number
20
Categorie Soggetti
Chemistry
Journal title
RUSSIAN CHEMICAL BULLETIN
ISSN journal
10665285 → ACNP
Volume
50
Issue
5
Year of publication
2001
Pages
901 - 906
Database
ISI
SICI code
1066-5285(200105)50:5<901:TPAROM>2.0.ZU;2-T
Abstract
The kinetics and pathways of thermolysis of the Co(II) complex with acrylam ide, [Co(CH2=CHCONH2)(4)(H2O)(2)](NO3)(2) (1) were studied. The rate of gas evolution is satisfactorily approximated by a first-order equation of auto catalysis. The composition of gaseous and solid products of thermolysis of 1 was studied by IR spectroscopy, mass spectrometry, and electronic microsc opy. Thermal transformations of acrylamide complex 1 include three macro st ages: dehydration, polymerization of the dehydrated monomer, and thermooxid ative destruction of the resulting polymer.