Addition of bromine to 2-methyl-2-azabicyclo[2.2.1]hept-5-ene

Authors
Bulanov, MN Sosonyuk, SE Zyk, NV
Citation
Mn. Bulanov et al., Addition of bromine to 2-methyl-2-azabicyclo[2.2.1]hept-5-ene, RUSS CHEM B, 50(5), 2001, pp. 917-918
Citations number
6
Categorie Soggetti
Chemistry
Journal title
RUSSIAN CHEMICAL BULLETIN
ISSN journal
10665285 → ACNP
Volume
50
Issue
5
Year of publication
2001
Pages
917 - 918
Database
ISI
SICI code
1066-5285(200105)50:5<917:AOBT2>2.0.ZU;2-J
Abstract
Addition of bromine to 2-methyl-2-azabicyclo[2.2.1]hept-5-ene was studied. Unexpectedly, 3-bromo-1-methyl-1-azoniatricyclo[2.2.1.0(2,6)]heptane tribro mide was isolated rather than the product of bromine addition to the double bond. The former reacted with the starting alkene in a polar solvent to fo rm the corresponding monobromide.