Unexpectedly high stability of benzaldehyde in the presence of Pd-561 giant cluster

Authors
Gladyi, SL Starchevsky, MK Pazdersky, YA Vargaftik, MN Moiseev, II
Citation
Sl. Gladyi et al., Unexpectedly high stability of benzaldehyde in the presence of Pd-561 giant cluster, RUSS CHEM B, 50(5), 2001, pp. 921-922
Citations number
6
Categorie Soggetti
Chemistry
Journal title
RUSSIAN CHEMICAL BULLETIN
ISSN journal
10665285 → ACNP
Volume
50
Issue
5
Year of publication
2001
Pages
921 - 922
Database
ISI
SICI code
1066-5285(200105)50:5<921:UHSOBI>2.0.ZU;2-P
Abstract
Benzyl alcohol is readily oxidized by O-2 to benzaldehyde in the presence o f catalytic amounts of the Pd(561)phen(60)(OAc)(180) giant cluster. Unlike aliphatic aldehydes, benzaldehyde is resistant toward further transformatio ns in this system.