Phosphacyclophanes derived from hydroquinone and 4,4 '-dihydroxybiphenyl

Authors
Nifant'ev, EE Rasadkina, EN Evdokimenkova, YB
Citation
Ee. Nifant'Ev et al., Phosphacyclophanes derived from hydroquinone and 4,4 '-dihydroxybiphenyl, RUSS J G CH, 71(3), 2001, pp. 366-372
Citations number
7
Categorie Soggetti
Chemistry
Journal title
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
ISSN journal
10703632 → ACNP
Volume
71
Issue
3
Year of publication
2001
Pages
366 - 372
Database
ISI
SICI code
1070-3632(200103)71:3<366:PDFHA4>2.0.ZU;2-Z
Abstract
The first representatives of linear phosphocyclophanes were prepared starti ng from hydroquinone or 4,4'-dihydroxybiphenyl and phosphorous triamides. T he reaction course is influenced by the structures of the aromatic diol and alkyl substituents in the phosphamide moiety. The phosphorus atom readily enters redox reactions and complexation. The complexing power of the aromat ic fragments of the synthesized molecules is lower than that of classical p -cyclophanes.