Micelle-forming and catalytic properties of n-alkyl(2-hydroxyethyl)dimethylammonium bromides in the phosphorylation of tetrakis(dimethylaminomethyl)calixresorcin[4]arene

Authors
Zhil'tsova, EP Timosheva, AP Shagidullina, RA Mustafina, AR Kudryavtseva, LA Kataev, VE Kazakova, EK Nikolaev, VF Konovalov, AI
Citation
Ep. Zhil'Tsova et al., Micelle-forming and catalytic properties of n-alkyl(2-hydroxyethyl)dimethylammonium bromides in the phosphorylation of tetrakis(dimethylaminomethyl)calixresorcin[4]arene, RUSS J G CH, 71(3), 2001, pp. 383-388
Citations number
17
Categorie Soggetti
Chemistry
Journal title
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
ISSN journal
10703632 → ACNP
Volume
71
Issue
3
Year of publication
2001
Pages
383 - 388
Database
ISI
SICI code
1070-3632(200103)71:3<383:MACPON>2.0.ZU;2-Q
Abstract
Micelle formation by n-alkyl(2-hydroxyethyl)dimethylammonium bromides in ch loroform was studied by dielcometric titration and kinetic method. Increase in the length of the hydrocarbon chain leads to reduced critical micelle c oncentration. The region of structural reorganization of micelles was deter mined. n-Alkyl(2-hydroxyethyl)dimethylammonium bromides catalyze phosphoryl ation of tetrakis(dimethylaminomethyl)calixresorcin[4]arene. The catalytic activity of micelles depends on the hydrophobic properties and concentratio n of the surface-active substance, as well as on structural features of its aggregates.