Crystal structure of lithium di(thiourea)ethylenediaminetetraacetatobismuthate(III) hydrate LiBi(Edta)(Tu)(2) center dot 5.5H(2)O

Authors
Davidovich, RL Gerasimenko, AV Logvinova, VB
Citation
Rl. Davidovich et al., Crystal structure of lithium di(thiourea)ethylenediaminetetraacetatobismuthate(III) hydrate LiBi(Edta)(Tu)(2) center dot 5.5H(2)O, RUSS J IN C, 46(8), 2001, pp. 1164-1171
Citations number
11
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
ISSN journal
00360236 → ACNP
Volume
46
Issue
8
Year of publication
2001
Pages
1164 - 1171
Database
ISI
SICI code
0036-0236(200108)46:8<1164:CSOLD>2.0.ZU;2-B
Abstract
The mixed-ligand Bi(III) complexonate with the ethylenediaminetetraacetate anion and thiourea molecules LiBi(Edta)(Tu)(2) . 5.5H(2)O was synthesized. The crystal structure of this compound was determined; it consists of Li(H2 O)(4)(+) cations, intricate complex anions [Bi(Edta)(Tu)(2)-Li(H2O)(2)-Bi(E dta)(Tu)(2)](-) (formed by linking two Bi(Edta)(Tu)(2)(-) complexes through the Li(H2O)(2)(+) cation), and crystal water molecules. The system of N-H . . .O and O-H . . .O hydrogen bonds combines the structural units into a t hree-dimensional framework.