Synthesis and structure of the iron(III) chloride complex with 1-morpholino-3,3-dimethyl-3,4-dihydroisoquinoline

Authors
Sokol, VI Ryabov, MA Merkur'eva, NY Sergienko, VS Davydov, VV Shklyaev, YV
Citation
Vi. Sokol et al., Synthesis and structure of the iron(III) chloride complex with 1-morpholino-3,3-dimethyl-3,4-dihydroisoquinoline, RUSS J IN C, 46(8), 2001, pp. 1199-1203
Citations number
5
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
ISSN journal
00360236 → ACNP
Volume
46
Issue
8
Year of publication
2001
Pages
1199 - 1203
Database
ISI
SICI code
0036-0236(200108)46:8<1199:SASOTI>2.0.ZU;2-C
Abstract
The iron(III) chloride complex with 1-morpholino-3,3-dimethyl-3,4-dihydrois oquinoline (1) was synthesized and characterized by X-ray crystallography a nd IR and electronic spectroscopy. Structure I is built of centrosymmetric binuclear [(FeCl3)(2)(mu -O)](2-) anions and (HL)(+) cations. The coordinat ion of the Fe3+ atom is tetrahedral. The bond lengths are Fe-O(br) 1.748 An gstrom, average Fe-Cl 2.221 Angstrom. The (HL)(+) cation is protonated at t he nitrogen atom of the dihydroisoquinoline moiety.