Ve. Gol'Eva et al., The kinetics of disproportionation of diiodohalides of organic nitrogen-containing cations in iodine-coordinating solvents, RUSS J PH C, 75(8), 2001, pp. 1255-1258
The disproportionation of diiodohalides of organic nitrogen-containing cati
ons in iodine-coordinating solvents was studied by electronic spectroscopy.
The kinetics of disproportionation of triethylbenzylammonium diiodochlorid
e and N-cetylpyridinium and tetrabutylammonium diiodobromides was determine
d in the chloroform-methanol (ethanol, acetonitrile) systems. A mechanism o
f mutual transformations of polyhalides was suggested, and the dependence o
f the rate constants of disproportionation on the nature of the solvent was
studied.