Mass crystallization of ellipsoidal particles from solutions under conditions of kinetically controlled crystal growth

Authors
Citation
Ai. Moshinskii, Mass crystallization of ellipsoidal particles from solutions under conditions of kinetically controlled crystal growth, RUSS J PH C, 75(8), 2001, pp. 1288-1296
Citations number
31
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY
ISSN journal
00360244 → ACNP
Volume
75
Issue
8
Year of publication
2001
Pages
1288 - 1296
Database
ISI
SICI code
0036-0244(200108)75:8<1288:MCOEPF>2.0.ZU;2-U
Abstract
Mass crystallization was described in terms of a crystal size distribution function (CSDF). Particles in the form of ellipsoids of revolution were con sidered. Needle-shaped and flattened (round) crystalline particles were con sidered limiting cases. The problem was reduced to the solution of a system of ordinary differential equations for the CSDF moments. The stationary so lution to the system was investigated for stability, and criteria of stabil ity were derived. It was shown that when stability is violated, oscillation s arise in the system. The characteristics of the oscillation regime were i llustrated by examples.