Evolution of ternary azeotropes caused by changes in external parameters

Citation
Av. Nikitskii et Tm. Kushner, Evolution of ternary azeotropes caused by changes in external parameters, RUSS J PH C, 75(8), 2001, pp. 1382-1387
Citations number
10
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY
ISSN journal
00360244 → ACNP
Volume
75
Issue
8
Year of publication
2001
Pages
1382 - 1387
Database
ISI
SICI code
0036-0244(200108)75:8<1382:EOTACB>2.0.ZU;2-2
Abstract
The conditions of realization of each of the three types of evolution of te rnary azeotropes during changes in external parameters were established. It was demonstrated that the concentration regions of location of ternary aze otropes are limited by lines of equal values of the activity coefficients o f the components and unit activity coefficient lines. It was established th at these boundaries can be transgressed by the composition of the azeotrope during its evolution in the presence of Bancroft points of required types.