The conditions of realization of each of the three types of evolution of te
rnary azeotropes during changes in external parameters were established. It
was demonstrated that the concentration regions of location of ternary aze
otropes are limited by lines of equal values of the activity coefficients o
f the components and unit activity coefficient lines. It was established th
at these boundaries can be transgressed by the composition of the azeotrope
during its evolution in the presence of Bancroft points of required types.