We have characterized the fundamental photoluminescence (PL) properties of
individual, isolated indium phosphide (InP) nanowires to define their poten
tial for optoelectronics. Polarization-sensitive measurements reveal a stri
king anisotropy in the PL intensity recorded parallel and perpendicular to
the long axis of a nanowire. The order-of-magnitude polarization anisotropy
was quantitatively explained in terms of the large dielectric contrast bet
ween these freestanding nanowires and surrounding environment, as opposed t
o quantum confinement effects. This intrinsic anisotropy was used to create
polarization-sensitive nanoscale photodetectors that may prove useful in i
ntegrated photonic circuits, optical switches and interconnects, near-field
imaging, and high-resolution detectors.