Magnetic and X-ray diffraction investigation on Mg1-xMn2+xO4 spinels

Citation
Cb. Azzoni et al., Magnetic and X-ray diffraction investigation on Mg1-xMn2+xO4 spinels, SOL ST COMM, 119(10-11), 2001, pp. 591-595
Citations number
12
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
SOLID STATE COMMUNICATIONS
ISSN journal
00381098 → ACNP
Volume
119
Issue
10-11
Year of publication
2001
Pages
591 - 595
Database
ISI
SICI code
0038-1098(2001)119:10-11<591:MAXDIO>2.0.ZU;2-4
Abstract
X-ray powder diffraction, electron paramagnetic resonance and static magnet isation measurements of slowly cooled Mg1-xMn2+xO4 solid solutions for 0 le ss than or equal to x less than or equal to 1 have been performed in order to investigate the effects of the Mg/Mn ratio on the spinel inversion. Our results prove that a small inversion degree exists at room temperature for the samples with x < 0.5 and suggest that the inversion decreases with incr easing x, that is by reducing the Mg2+ content. The multi-technique approac h for the definition of the correct synthetic and cooling procedures enable s the formation of single-phase high purity materials. (C) 2001 Elsevier Sc ience Ltd. All rights reserved.