A novel approach to fluoro-containing alkenes

Authors
Korotchenko, VN Shastin, AV Nenajdenko, VG Balenkova, ES
Citation
Vn. Korotchenko et al., A novel approach to fluoro-containing alkenes, TETRAHEDRON, 57(35), 2001, pp. 7519-7527
Citations number
31
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON
ISSN journal
00404020 → ACNP
Volume
57
Issue
35
Year of publication
2001
Pages
7519 - 7527
Database
ISI
SICI code
0040-4020(20010827)57:35<7519:ANATFA>2.0.ZU;2-N
Abstract
A new and general one-pot transformation of aromatic aldehydes to fluorinat ed olefins containing -CH=C(Cl)CF3 or -CH=C(F)CClF2 moieties is described. Freons CCl3CF3 and CCl2FCCIF2 were used as trifluoromethyl and difluorometh yl C-2-building blocks respectively. A proposed mechanism for the reaction is discussed. (C) 2001 Elsevier Science Ltd. Ali rights reserved.