Application of 2-ethylpyrrole for a direct synthesis of 3-substituted inverted porphyrins

Authors
Schmidt, I Chmielewski, PJ
Citation
I. Schmidt et Pj. Chmielewski, Application of 2-ethylpyrrole for a direct synthesis of 3-substituted inverted porphyrins, TETRAHEDR L, 42(36), 2001, pp. 6389-6392
Citations number
14
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
42
Issue
36
Year of publication
2001
Pages
6389 - 6392
Database
ISI
SICI code
0040-4039(20010903)42:36<6389:AO2FAD>2.0.ZU;2-H
Abstract
3-Ethly-5,10,15,20-tetraphenyl-2-aza-21-carbaporphyrin is the major macrocy clic product in the condensation of 2-ethylpyrrole, pyrrole, and benzaldehy de. Oxidation of the ethyl substituent leads to 3-(1 ' -hydroxyethyl)- and 3-acetyl-substituted inverted porphyrins. (C) 2001 Elsevier Science Ltd. Al l rights reserved.