First enantioselective total synthesis of both enantiomers of lancifolol. Correlation: Absolute configuration/specific rotation

Authors
Galano, JM Audran, G Monti, H
Citation
Jm. Galano et al., First enantioselective total synthesis of both enantiomers of lancifolol. Correlation: Absolute configuration/specific rotation, TETRAHEDR L, 42(35), 2001, pp. 6125-6128
Citations number
33
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
42
Issue
35
Year of publication
2001
Pages
6125 - 6128
Database
ISI
SICI code
0040-4039(20010827)42:35<6125:FETSOB>2.0.ZU;2-L
Abstract
The first enantioselective total synthesis of both enantiomers of lancifolo l has been accomplished using a Z-stereoselective Peterson olefination and a palladium-catalyzed cross-coupling reaction Lis key steps. This approach allows us to correlate the relationship between absolute configuration an s pecific rotation, to date both Unknown. (C) 2001 Elsevier Science Ltd. All rights reserved.