Synthetic studies towards gambierol. Part 1: Synthesis of the AB ring segment

Authors
Kadota, I Park, CH Sato, K Yamamoto, Y
Citation
I. Kadota et al., Synthetic studies towards gambierol. Part 1: Synthesis of the AB ring segment, TETRAHEDR L, 42(35), 2001, pp. 6195-6197
Citations number
11
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
42
Issue
35
Year of publication
2001
Pages
6195 - 6197
Database
ISI
SICI code
0040-4039(20010827)42:35<6195:SSTGP1>2.0.ZU;2-A
Abstract
The AB ring segment of gambierol (1) was synthesized from 2-deoxy-D-ribose in 23 steps. The key steps were Brown's asymmetric allylboration of the ald ehyde 5 and the intramolecular hetero-Michael reaction of 7. (C) 2001 Elsev ier Science Ltd. All rights reserved.