Di[(S)-1-(9-anthryl)-2,2,2-trifluoroethyl]sulphite, a case of diastereotopic anthracene groups

Authors
Sanchez, M Maestre, I Jaime, C Virgili, A
Citation
M. Sanchez et al., Di[(S)-1-(9-anthryl)-2,2,2-trifluoroethyl]sulphite, a case of diastereotopic anthracene groups, TETRAHEDR-A, 12(12), 2001, pp. 1737-1740
Citations number
9
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON-ASYMMETRY
ISSN journal
09574166 → ACNP
Volume
12
Issue
12
Year of publication
2001
Pages
1737 - 1740
Database
ISI
SICI code
0957-4166(20010716)12:12<1737:DACOD>2.0.ZU;2-V
Abstract
The conformation of di[(S)-1-(9-anthryl)-2,2,2-trifluoroetliyl]sulphite 1 w as determined from NMR data and Monte-Carlo conformational search and molec ular dynamics calculations. The two diastereotopic ring systems adopt an al most perpendicular relative position. (C) 2001 Elsevier Science Ltd. (C) Al l rights reserved.