THIIRANIUM AND THIIRENIUM IONS - FROM REACTION INTERMEDIATES TO BUILDING-BLOCKS IN ORGANIC-SYNTHESIS

Authors
LUCCHINI V MODENA G PASQUATO L
Citation
V. Lucchini et al., THIIRANIUM AND THIIRENIUM IONS - FROM REACTION INTERMEDIATES TO BUILDING-BLOCKS IN ORGANIC-SYNTHESIS, Gazzetta chimica italiana, 127(4), 1997, pp. 177-188
Citations number
194
Categorie Soggetti
Chemistry
Journal title
Gazzetta chimica italiana → ACNP
ISSN journal
00165603
Volume
127
Issue
4
Year of publication
1997
Pages
177 - 188
Database
ISI
SICI code
0016-5603(1997)127:4<177:TATI-F>2.0.ZU;2-6
Abstract
The chemistry of thiiranium and thiirenium ions, examples of iranium a nd irenium ions, is discussed in the light of recent reactivity data o btained on isolated ions. An overview of the use of thiiranium and sel eniranium ions in organic synthesis as useful building blocks to contr ol the regio- and the stereochemistry of several processes is presente d.