RADIATION-CHEMICAL INVESTIGATIONS ON AQUEOUS-SOLUTIONS OF C-60(OH)(18)

Authors
MOHAN H CHIANG LY MITTAL JP
Citation
H. Mohan et al., RADIATION-CHEMICAL INVESTIGATIONS ON AQUEOUS-SOLUTIONS OF C-60(OH)(18), Research of chemical intermediates, 23(5), 1997, pp. 403-414
Citations number
37
Categorie Soggetti
Chemistry
Journal title
Research of chemical intermediates → ACNP
ISSN journal
09226168
Volume
23
Issue
5
Year of publication
1997
Pages
403 - 414
Database
ISI
SICI code
0922-6168(1997)23:5<403:RIOAOC>2.0.ZU;2-7
Abstract
The ultraviolet-visible absorption spectrum of C-60(OH)(18) in water s howed an absorption band with lambda(max) = 215 nm and other character istic absorption bands of C-60 are not observed. The singlet-singlet a nd triplet-triplet absorption bands are not observed in the 400 - 900 nm region. It has Low reactivity with e(aq)(-) and formed an absorptio n band with lambda(max) = 580 nm. The hydroxyl radicals react with a b imolecular rate constant of 2.4 x 10(9) dm(3) mol(-1) s(-1) and showed an absorption band at 540 nm.