The aim of the present study is to suggest two new fluids as alternati
ves of R12 in a vapour compression cycle. These fluids are the methyl
trifluoromethyl ether (E143a) and the hexafluorocyclopropane (C216), w
hich belong to halogenated derivatives of dimethyl ether and cycloprop
ane, respectively. The two suggested fluids have low degree of toxicit
y and a quite short atmospheric life. They also have suitable boiling
points and a relatively simple molecular structure. A method of estima
tion of the thermodynamic properties of E143a and C216 is presented, T
he theoretical performance of the new fluids are evaluated and compare
d to those of the R12.