Viscoelastic properties of plasticized methylcellulose and chemically crosslinked methylcellulose

Films of methylcellulose (MC), poly(ethylene glycol)400 (PEG400) plasticize d MC, and MC gels (MC crosslinked with glutaraldehyde (GA)) were prepared b y casting from aqueous solutions. The swelling test has shown that the MC g els were insoluble in water and that their crosslinking density increased w ith increasing GA and HCl concentrations. The effect of the addition of PEG 400 or GA to MC was investigated through dynamic mechanical analysis (DMA). The DMA analysis of PEG400/MC blends has shown that PEG400 was compatible with MC and was an effective plasticizer since the curves of tan delta agai nst temperature exhibited single peaks (corresponding to a single glass tra nsition temperature), which were displaced to lower values with increasing PEG400 content. The thermogravimetric analysis (TGA) indicated that the the rmal stability of MC was not affected by the chemical crosslinking. The ten sile strength was slightly increased through crosslinking while the elongat ion was slightly decreased. The presence of moisture in MC hydrogels decrea sed the tensile strength and enhanced the elongation while the addition of PEG400 decreased the tensile strength but sharply increased the elongation. (C) 2001 Elsevier Science Ltd. All rights reserved.