Magnesium bisamides as reagents in synthesis

Citation
Kw. Henderson et Wj. Kerr, Magnesium bisamides as reagents in synthesis, CHEM-EUR J, 7(16), 2001, pp. 3430-3437
Citations number
41
Categorie Soggetti
Chemistry
Journal title
CHEMISTRY-A EUROPEAN JOURNAL
ISSN journal
09476539 → ACNP
Volume
7
Issue
16
Year of publication
2001
Pages
3430 - 3437
Database
ISI
SICI code
0947-6539(20010817)7:16<3430:MBARIS>2.0.ZU;2-Z
Abstract
As part of the continued requirement for more selective reagents in organic synthesis, magnesium bis-amides are becoming established as a class of org anometallic bases with considerable potential. Their relatively mild reacti vity, combined with their high degree of steric congestion, leads to a dist inct class of reagents with significantly different chemo-, regio-, stereo- and enantioselectivities when compared with existing species and protocols .