Hyperbranched aromatic polymers obtained via self-condensation

Authors
Zhang, X Chen, YM Wang, DY Jiang, J Liu, HW Chen, CF Xi, F
Citation
X. Zhang et al., Hyperbranched aromatic polymers obtained via self-condensation, CHIN J POLY, 19(5), 2001, pp. 517-520
Citations number
11
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
CHINESE JOURNAL OF POLYMER SCIENCE
ISSN journal
02567679 → ACNP
Volume
19
Issue
5
Year of publication
2001
Pages
517 - 520
Database
ISI
SICI code
0256-7679(200109)19:5<517:HAPOVS>2.0.ZU;2-Q
Abstract
Hyperbranched aromatic polymers were prepared by Friedel-Crafts reaction wi th Lewis acid, AlCl3 and ZnCl2, as the catalysts. In this work, hyperbranch ed polybenzyl (PB) and poly(methylene)naphthalene (PN) were synthesized and characterized by H-1-NMR and GPC. In addition, their florescence propertie s were measured with steady-state florescence spectra in THF and ethylene d ichloride. The quantum yields of polybenzyl and poly(methylene)naphthalene in ethylene dichloride are much larger than those in THE.