Airborne lidar measurements reveal a case in which a layer of high-ozone ai
r extruding from a tropopause fold appears to cap a pollution plume and for
ce it to spread out in the lower troposphere. The morphology of the high-oz
one layer resembles a three-dimensional model of tropopause fold evolution
that produces a low-altitude potential vorticity tube. This is a mechanism
that can complete the irreversible transfer of air from the stratosphere, a
nd can also affect pollution levels at the surface if the capping layer rea
ches the top of the boundary layer.