A study was conducted to evaluate the extent of thermo-oxidative degradatio
n in different types of oils (sunflower, soybean, peanut, and virgin of oli
ve) microwave heated in model systems. The acidity determination, peroxide
value, specific UV spectrophotometric constants, and p-anisidine value - us
eful for a basic evaluation - were carded out, Polar compounds and the sing
le classes of substances constituting them were also determined to better e
stimate the extent of oxidative and hydrolytic degradation of the oils unde
r study. The obtained results showed a high oxidative degradation degree of
the oils that, however, seemed to be correlated to the poly-enoic fatty ac
id content and to the presence of pro-oxidant substances. The hydrolytic de
gradation, otherwise, resulted moderate.