Unusual complexes formed by the early lanthanides with 2,6-bis(5,6-dialkyl-1,2,4-triazin-3-yl)-pyridines

Authors
Drew, MGB Guillaneux, D Hudson, MJ Iveson, PB Madic, C
Citation
Mgb. Drew et al., Unusual complexes formed by the early lanthanides with 2,6-bis(5,6-dialkyl-1,2,4-triazin-3-yl)-pyridines, INORG CH C, 4(9), 2001, pp. 462-466
Citations number
25
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS
ISSN journal
13877003 → ACNP
Volume
4
Issue
9
Year of publication
2001
Pages
462 - 466
Database
ISI
SICI code
1387-7003(200109)4:9<462:UCFBTE>2.0.ZU;2-Z
Abstract
The addition of lanthanide(III) nitrates (La-Sm) to the actinide(III) extra cting agents, 2,6-bis(5,6-dialkyl-1,2,4-triazin-3-yl)-pyridines in a 1:1 ra tio, results in the crystallisation of unusual dimeric complexes [Ln(2)(L-1 )(2)(NO3)(6)] as well as more usual mononuclear complexes. (C) 2001 Elsevie r Science B.V. All rights reserved.