A three-dimensional framework of dimeric copper(II) acetate linked by coordinated sodium cations

Authors
Wu, CD Lu, CZ Yang, WB Zhuang, HH Huang, JS
Citation
Cd. Wu et al., A three-dimensional framework of dimeric copper(II) acetate linked by coordinated sodium cations, INORG CH C, 4(9), 2001, pp. 504-506
Citations number
30
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS
ISSN journal
13877003 → ACNP
Volume
4
Issue
9
Year of publication
2001
Pages
504 - 506
Database
ISI
SICI code
1387-7003(200109)4:9<504:ATFODC>2.0.ZU;2-2
Abstract
The reaction of a DMSO solution of Cu(OCOCH3)(2) . H2O with CH3COONa . 3H(2 )O in the presence of acetate acid gives the formation of sodium cations li nking six-coordinated copper(II) acetates into microporous network structur e, NaHCu2(OCOCH3)(6) 1. The powder ESR of I reveals that there might exist exchange interactions between these copper(II) cations. (C) 2001 Published by Elsevier Science B.V.