Fe thin films with flat surfaces are obtained on a MgO(001) substrate at a
growth temperature of 550K. The surfaces with atomically flat and wide terr
aces exhibit a c(2x2) reconstructed structure. To evaluate the effect of im
purity atoms at the surface on the surface structures, scanning tunneling s
pectroscopy (STS), reflection high energy electron diffraction (RHEED) and
X-ray photoelectron spectroscopy (XPS) studies were performed. The differen
tial conductivity (dI/dV) spectrum of the c(2x2) Fe(001) thin-film surfaces
indicates an intense peak at the sample bias voltage of 0.4V. Since there
is no clear evidence of impurity adatoms forming such a surface structure,
we expect that the topmost atoms are Fe, and that the observed peak origina
tes from surface states.