T. Sugizaki et al., Dual-thickness gate oxidation technology with halogen/xenon implantation for embedded dynamic random access memories, JPN J A P 1, 40(4B), 2001, pp. 2674-2678
We investigated the enhanced oxidation effect of using silicon (Si) implant
ed with fluorine (F), iodine (I), and xenon (Xe) before gate oxidation. I a
nd Xe, which result in shallower implants because of their higher mass numb
ers, were expected to be less damaging to the Si substrate. The resultant i
ncrease in oxide thickness was found to be 20%, 80%, and 50% under F, I, an
d Xe implantations with a dose of 5 x 10(14) CM-2, respectively. We found t
hat F atoms outdiffuse to their ambient through SiO2, and that I implantati
on causes the greatest increase in oxide thickness. In addition, F implanta
tion shows highly reliable dielectric characteristics, low contact resistan
ce, and a low junction leakage current. Consequently, the F implantation pr
ocess is capable of providing reliable dual-thickness gate ox-ide for embed
ded dynamic random access memories (DRAMs).