Layered LiFeO2 is an antiferromagnet with a Neel temperature T-N = 20 K. Su
bstituting Fe with diamagnetic Co3+ surprisingly leads first (up to x = 0.4
). to an increase of the Weiss temperature theta and then above x = 0.4 to
a decrease due to a dilution effect. Magnetic properties are qualitatively
interpreted within a mean field model. with ferromagnetic layers coupled an
tiferromagnetically. Estimation is given of the ferro- and antiferromagneti
c interactions. (C) 2001 Elsevier Science B.V. All rights reserved.