Optical second-harmonic (SH) spectroscopy is introduced as a powerful suppl
ement for the determination of complex magnetic structures. Experimental ef
forts are simplified and new degrees of freedom are opened. Thereby, some p
rincipal or technical restrictions of neutron or magnetic X-ray diffraction
experiments are overcome. As an example, various antiferromagnetic compoun
ds of the Mn3+ and Cr3+ ions are discussed. (C) 2001 Elsevier Science B.V.
All rights reserved.