W. Saikaly et al., The effects of thermomechanical processing on the precipitation in an industrial dual-phase steel microalloyed with titanium, MET MAT T A, 32(8), 2001, pp. 1939-1947
Analytical transmission electron microscopy was employed to characterize th
e precipitation at each step of the fabrication process and thermomechanica
l treatment of an industrial dual-phase steel microalloyed with titanium. T
heoretical thermodynamic calculations as well as experimental analysis show
ed that more than half of the titanium carbosulfide (Ti4C2S2) precipitates
would dissolve during reheating at 1240 degreesC. Despite this dissolution
at 1240 degreesC, the remaining titanium carbonitrides and carbosulfides we
re effective in pinning austenitic grain boundaries, keeping the austenitic
grain size at around 40 mum (at 1240 degreesC). It is also shown that, dur
ing hot rolling, there exist three regions of titanium carbide precipitatio
n. The first is defined by an increase of titanium carbide precipitation du
e to deformation. The second region is marked by the insignificant change i
n precipitation. The third region is indicated by another increase in preci
pitation due to the austenite-to-ferrite transformation. The experimental a
nd theoretical results on the contribution of TiC precipitation to hardenin
g of ferrite (Orowan mechanism) were in excellent agreement, showing that T
iC precipitates have the most important effect on increasing the yield stre
ngth, overshadowing the austenitic grain-boundary pinning contributions by
Ti(C,N) and Ti4C2S2 precipitates.