During the recombination epoch, cosmic background photons coupled not only
to free electrons through Thompson scattering, but also to neutral hydrogen
through Rayleigh scattering. This latter is a similar to2% effect for phot
ons near the peak of the photon energy distribution at z = 800 and a simila
r to0.2% effect at z = 1100. Including Rayleigh scattering in the calculati
on reduces Silk damping at fixed redshift, alters the position of the surfa
ce of last scattering, and alters the propagation of acoustic waves. We est
imate the amplitude of these effects. For the Microwave Anisotropy Probe (M
AP), Rayleigh scattering increases the anisotropy spectrum by 0.1% at the m
ost. For the highest frequencies of the Planck Surveyor, the effects of Ray
leigh scattering are much more dramatic (decreasing the anisotropy spectrum
by 3% at v similar to 550 GHz and multipole number l similar to 1000). The
relative difference between the spectra of low and high frequencies is imp
osed by an oscillation with a function of multipole l, and the oscillation
amplitude is up to 0.5% between 100 and 550 GHz. Rayleigh scattering also s
lows the decoupling between radiation and matter, but the effect is undetec
tably small.